We observed the complete massive star population associated with the N206 superbubble on 2015 December 19-20 with VLT-FLAMES. The observation was carried out using three of the standard settings of the Giraffe spectrograph LR02 (resolving power R=6000, 3960-4567Å), LR03 (R=7500, 4501-5071Å), and HR15N (R=19200, 6442-6817Å), respectively. We took three to six exposures (30 min each) for each pointing in three spectrograph setting to improve the S/N. Ultraviolet (UV) spectra are available for three Of stars in our sample, and we retrieved these from the Mikulski Archive for Space Telescopes (MAST3). The stellar and wind parameters of individual OB stars derived from spectral analysis using PoWR models. (1 data file).